Cambridge IGCSE · Topic 7.1
IGCSE Chemistry 0620 / Topic 7 / IGCSE

Giving away a proton.

A hydrogen ion is just a proton. So an acid is anything that gives away protons and a base is anything that takes them. How completely an acid gives them away decides whether it is strong or weak, which is not the same as concentrated or dilute. Extended content.

The key idea

Extended. An acid is a proton donor and a base is a proton acceptor, because an H+ ion is a proton. A strong acid is completely dissociated in water: HCl(aq) → H+(aq) + Cl−(aq). A weak acid is only partially dissociated: CH3COOH(aq) ⇌ H+(aq) + CH3COO−(aq). At the same concentration a weak acid has fewer H+ ions, a higher pH and reacts more slowly.

strong: hydrochloric acid weak: ethanoic acid H⁺Cl⁻H⁺Cl⁻ Cl⁻H⁺Cl⁻H⁺ H⁺Cl⁻H⁺Cl⁻ CH₃COOHCH₃COOH CH₃COOHCH₃COOH CH₃COOH H⁺CH₃COO⁻ completely dissociated HCl → H⁺ + Cl⁻ partially dissociated CH₃COOH ⇌ H⁺ + CH₃COO⁻
Fig. 1: complete and partial dissociation
Section 01

Proton donors and acceptors.

Extended content. A hydrogen atom that loses its electron leaves just a proton, so H+ and "proton" mean the same thing.

Stage 1 · Learn

Check what the sim just showed you

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(Extended) An acid is defined as:

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(Extended) A weak acid is one that:

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(Extended) In NH3 + H+ → NH4+, ammonia acts as:

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(Extended) Which of these is a strong acid?

Section 02

Strong and weak.

Compare hydrochloric acid and ethanoic acid of the same concentration in the simulator. Look at the pH and at how many molecules have split into ions.

Same concentration, 0.1 mol/dm3Hydrochloric acid (strong)Ethanoic acid (weak)
dissociationcompletepartial
H+ concentrationhighlow
pHabout 1about 3
with magnesiumvigorous fizzingslow fizzing
electrical conductivitygoodpoor

Other strong acids: sulfuric and nitric acid. Other weak acids: citric acid and carbonic acid. With enough time, the same amount of each acid still produces the same total amount of hydrogen with excess magnesium, because the weak acid keeps dissociating as its H+ ions are used up.

Examiner trap

Strong and concentrated are different ideas. Strength is about how completely the acid dissociates; concentration is about how much acid is dissolved per dm3. A dilute solution of a strong acid and a concentrated solution of a weak acid are both possible.

Stage 2 · Exam

Exam-style questions

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(Extended) Hydrochloric acid and ethanoic acid of the same concentration are compared. Which statement is correct?

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(Extended) Which equation shows ethanoic acid acting as a weak acid in water?

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(Extended) Equal volumes of 0.1 mol/dm3 hydrochloric acid and 0.1 mol/dm3 ethanoic acid react with excess magnesium ribbon. What is observed?

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(Extended) Which statement correctly distinguishes a concentrated weak acid from a dilute strong acid?

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Six original Cambridge-style questions
Acids as proton donors and bases as proton acceptors, complete and partial dissociation, comparing strong and weak acids, and strength versus concentration. Extended content.