Cambridge IGCSE · Topic 2.2
IGCSE Chemistry 0620 / Topic 2 / IGCSE

A tiny nucleus, a cloud of shells.

Every atom has the same three ingredients: protons, neutrons and electrons. Count them and you know the element; arrange the electrons in shells and you know where it sits in the Periodic Table and how it will react.

The key idea

An atom has a small central nucleus of protons and neutrons, surrounded by electrons in shells. The proton number (atomic number) is the number of protons; in a neutral atom it also equals the number of electrons. The mass number (nucleon number) is protons plus neutrons. Electrons fill shells in order: 2 in the first, then 8, then 8 for the first 20 elements. The number of outer-shell electrons gives the group (I to VII), and the number of occupied shells gives the period.

Na nucleus11 protons12 neutrons shell 1: 2 electronsshell 2: 8 electronsshell 3: 1 electron sodium: proton number 11, so 11 electrons arranged 2,8,1 1 outer electron: Group I. 3 occupied shells: Period 3.
Fig. 1: a sodium atom, electronic configuration 2,8,1
Section 01

Inside the atom.

Build an atom in the simulator. Add protons and watch the element change; add neutrons and only the mass changes; add or remove electrons and the atom becomes a charged ion.

ParticleWhere it isRelative chargeRelative mass
protonnucleus+11
neutronnucleus01
electronshells around the nucleus−11/1836
Section 02

Proton number and mass number.

The symbol 2311Na carries two numbers. The bottom one is the proton number, the top one the mass number.

Examiner trap

The mass number is not the number of neutrons. It counts protons and neutrons together, so always subtract: neutrons = mass number − proton number. Also check which number is which: the mass number is always the larger one.

Stage 1 · Learn

Check what the sim just showed you

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What is the relative mass of an electron?

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Where are the neutrons in an atom?

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How many neutrons are in an atom of 2311Na?

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The proton number of an atom is the number of:

Section 03

Shells and the Periodic Table.

Fill the shells in order, 2 then 8 then 8, and the Periodic Table's layout appears on its own.

ElementProton numberConfigurationGroupPeriod
helium, He22VIII1
carbon, C62,4IV2
oxygen, O82,6VI2
neon, Ne102,8VIII2
sodium, Na112,8,1I3
chlorine, Cl172,8,7VII3
argon, Ar182,8,8VIII3
potassium, K192,8,8,1I4
calcium, Ca202,8,8,2II4
Stage 2 · Exam

Exam-style questions

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How many protons, neutrons and electrons are in an atom of 2713Al?

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An atom has the electronic configuration 2,8,6. Which element is it, and where is it in the Periodic Table?

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What is the electronic configuration of calcium (proton number 20)?

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Why are the noble gases unreactive?

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Atomic structure, mastered.

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Go deeper · practice
Six original Cambridge-style questions
Relative charges and masses of the sub-atomic particles, counting protons, neutrons and electrons, electronic configurations, and using them to find group and period.