Cambridge IGCSE · Topic 12.4
IGCSE Chemistry 0620 / Topic 12 / IGCSE

Pull the mixture apart.

Salt from sea water, pure water from ink, ethanol from a fermented mixture: each separation uses a difference in property, whether solubility, particle size or boiling point. Pick the difference and the method follows. Then use melting and boiling points to check the product is pure.

The key idea

Choose a separation method from the difference between the substances. Filtration separates an insoluble solid from a liquid. Crystallisation obtains a soluble solid from its solution: heat to evaporate some solvent until the solution is saturated, then cool so crystals form. Simple distillation separates a solvent from a solution (for example water from salt water). Fractional distillation separates miscible liquids with different boiling points (for example ethanol and water). Dissolving in a suitable solvent separates a soluble solid from an insoluble one. A pure substance melts and boils at fixed, sharp temperatures; impurities lower the melting point and make it melt over a range, and raise the boiling point. Purity matters for food and drugs.

thermometer bulblevel with side arm water out water in distillate heat simple distillation liquid boils off, then thevapour condenses solution condenser
Fig. 1: simple distillation of a solution
Section 01

Choosing a method.

Name the mixture, find the property that differs, then choose.

MixtureDifference usedMethod
insoluble solid in a liquid (sand and water)particle size: solid cannot pass through the paperfiltration
soluble solid in solution (copper(II) sulfate solution)solid is left as the solvent evaporatescrystallisation
solvent from a solution (pure water from sea water)water boils, salt does notsimple distillation
miscible liquids (ethanol and water; crude oil)different boiling pointsfractional distillation
soluble and insoluble solids (salt and sand)solubility in a suitable solventdissolve, filter, then crystallise the filtrate
coloured substances in solution (dyes in ink)solubility in solvent and attraction to paperchromatography
Stage 1 · Learn

Check what the sim just showed you

Four quick checks. Each correct answer earns XP and records this skill on your profile.

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Which method separates sand from water?

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Which method obtains pure water from sea water?

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Which method separates ethanol from a mixture with water?

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How is a pure substance recognised from its melting point?

Section 02

Distillation and purity.

The two distillations differ in one piece of apparatus: the fractionating column.

Examiner trap

Do not heat a solution to dryness when crystallising a hydrated salt: you lose the water of crystallisation and may decompose it. Condenser water goes in at the bottom so the jacket stays full. Impurities lower the melting point (and widen the range) but raise the boiling point.

Stage 2 · Exam

Exam-style questions

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Pure aspirin melts at 136 °C. Which melting range shows an impure sample?

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How is pure salt obtained from a mixture of salt and sand?

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In simple distillation, why does cooling water enter the condenser at the bottom?

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Hydrated copper(II) sulfate crystals are made from the solution. Why is the solution not heated to dryness?

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Go deeper · practice
Six original Cambridge-style questions
Choosing and describing separation methods, distillation apparatus, crystallisation and using melting and boiling points to judge purity.