Cambridge IGCSE · Topic 9.5
IGCSE Chemistry 0620 / Topic 9 / IGCSE

Keep out air and water.

Rust costs a fortune in repairs every year, and it needs just two things: oxygen and water. Take away either one and iron stays shiny. Every prevention method either puts up a barrier or gives the oxygen something more reactive to attack.

The key idea

Iron and steel rust only when both water and oxygen are present; rust is hydrated iron(III) oxide. Barrier methods (painting, greasing, coating with plastic) stop rusting by keeping out water and oxygen. Galvanising coats iron with zinc. Extended: zinc, or a block of magnesium, gives sacrificial protection: being more reactive, it loses electrons and corrodes instead of the iron, even if the surface is scratched.

air and water boiled water, oil layer dry air rustsno rust (no oxygen)no rust (no water) calcium chloride iron rusts only when both oxygen and water are present
Fig. 1: the experiment showing that rusting needs both oxygen and water
Section 01

What rusting needs.

Three iron nails, three test tubes, one week: only one nail rusts.

Stage 1 · Learn

Check what the sim just showed you

Four quick checks. Each correct answer earns XP and records this skill on your profile.

Quick check+10 XP

Which two substances are needed for iron to rust?

Quick check+10 XP

What is rust?

Quick check+10 XP

Why is a bicycle chain greased rather than painted?

Quick check+10 XP

What is galvanising?

Section 02

Preventing rust.

Match the method to the object: paint for a bridge, grease for a bicycle chain, galvanising for a dustbin or a fence.

MethodHow it worksExample
paintingbarrier to water and oxygenbridges, cars
greasing or oilingbarrier; suitable for moving partsbicycle chains, tools
plastic coatingbarriergarden fencing, dish racks
galvanising (zinc coating)barrier, and sacrificial protection if scratcheddustbins, roofing, nails
sacrificial blocks (Extended)more reactive metal corrodes insteadzinc or magnesium blocks on ship hulls
Examiner trap

A barrier only works while it is unbroken: once paint is scratched, iron underneath rusts. Galvanising protects even when scratched because zinc is more reactive than iron and corrodes in its place. Tin-plating does the opposite: tin is less reactive, so a scratched tin can rusts faster.

Stage 2 · Exam

Exam-style questions

Unlocks once the four checks above are done. Worth more XP, written to IGCSE Paper 2 and Paper 4 standard.

Finish the four checks above to unlock the exam questions
Exam style+20 XP

In the rusting experiment, why is the water in one tube boiled and covered with oil?

Exam style+20 XP

(Extended) Why does galvanised iron not rust even when the zinc coating is scratched?

Exam style+20 XP

(Extended) Blocks of which metal could be attached to a steel ship's hull for sacrificial protection?

Exam style+20 XP

Which condition would make an iron nail rust fastest?

Skill unlocked

Rusting and its prevention, mastered.

This skill is now recorded on your profile. Keep the chain going.

-Rank -Level -Score -Topics
Go deeper · practice
Six original Cambridge-style questions
The conditions for rusting and the experiment that shows them, barrier methods, galvanising and sacrificial protection.