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Chemical energetics

IGCSE Chemistry 0620 · Topic 5 revision notes

Everything from the 3 lessons of this topic on a few pages: the key idea of each lesson, the diagram to remember, the points to learn and the traps examiners set. Read it, cover it, test yourself.

  1. Exothermic and endothermic reactions
  2. Reaction pathway diagrams
  3. Bond breaking, bond making and bond energies

1Exothermic and endothermic reactions

Syllabus 5.1

An exothermic reaction transfers thermal energy to the surroundings, so the temperature of the surroundings increases. An endothermic reaction takes in thermal energy from the surroundings, so the temperature of the surroundings decreases. Extended: the transfer of thermal energy during a reaction is the enthalpy change, ΔH. ΔH is negative for exothermic reactions and positive for endothermic reactions.

exothermic 21 °C → 29 °C heat out endothermic 21 °C → 14 °C heat in the thermometer measures the surroundings
Fig. 1: the temperature of the surroundings tells you the direction of energy transfer

Exo out, endo in.

  • Exothermic: energy to the surroundings; temperature rises.
  • Endothermic: energy from the surroundings; temperature falls.
  • Extended: ΔH negative for exothermic, positive for endothermic.
  • Reverse the reaction, reverse the sign of ΔH.

Watch out!

In an endothermic reaction the chemicals gain energy, but the thermometer shows a fall, because it measures the surroundings, which have lost energy. Do not say an endothermic reaction "gives out cold": cold is not a form of energy.

2Reaction pathway diagrams

Syllabus 5.1

On a reaction pathway diagram, if the products are lower in energy than the reactants the reaction is exothermic; if the products are higher it is endothermic. Extended: the enthalpy change ΔH is the difference in energy between reactants and products. The activation energy, Ea, is the minimum energy that colliding particles need in order to react; it is the height of the hill from the reactants to the top.

energy energy reactantsproducts reactantsproducts Eₐ ΔH Eₐ ΔH exothermic, ΔH negative endothermic, ΔH positive progress of reaction →
Fig. 1: reaction pathway diagrams for an exothermic and an endothermic reaction

Start every arrow at the reactants.

  • Products lower: exothermic. Products higher: endothermic.
  • Ea: reactants up to the top of the hill.
  • ΔH: reactants to products; down is negative, up is positive.
  • Catalyst: lower hill, same ΔH.

Watch out!

The activation energy arrow starts at the reactants, not at the bottom axis and not at the products. And ΔH is measured between the reactant and product levels, not from the top of the hill. Arrows drawn from the axis lose the mark.

3Bond breaking, bond making and bond energies

Syllabus 5.1

Extended. Bond breaking is endothermic: energy must be taken in to separate atoms. Bond making is exothermic: energy is released when atoms join. ΔH = energy needed to break bonds − energy released making bonds. If more energy is released making the new bonds than is needed to break the old ones, ΔH is negative and the reaction is exothermic.

energy H₂ + Cl₂ 2H + 2Cl (separate atoms) 2HCl break bonds +679 kJ make bonds −864 kJ ΔH ΔH = 679 − 864 = −185 kJ/mol more energy released making bonds than taken in breaking them: exothermic
Fig. 1: breaking and making bonds in H2 + Cl2 → 2HCl

Broken minus made.

  • Draw displayed formulae and count every bond.
  • Multiply by the numbers in the equation.
  • ΔH = bonds broken − bonds made.
  • Negative: exothermic. Positive: endothermic.

Watch out!

Multiply each bond energy by the number of those bonds, including the big numbers in the equation: 2O2 means two O=O bonds, and CO2 has two C=O bonds. And always subtract in the order broken − made. Doing it the other way round gives the right number with the wrong sign.

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