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9701 AS Chemistry/ Topic 17 Carbonyl compounds/ 5 interactive simulations/ drag to rotate 3D scenes

Carbonyl compounds, made interactive

Five simulations covering Topic 17: the carbonyl group in 3D with its pi bond and its dipole, the oxidation ladder from alcohol to aldehyde to acid and back down with sodium borohydride, the nucleophilic addition of hydrogen cyanide stepped through in 3D, the four bench tests that tell aldehydes from ketones, and an unknown to identify from its test results.

1. The carbonyl group 3D · 17.1

A carbon double bonded to an oxygen. The carbon is trigonal planar, the pi bond sits above and below that plane, and because oxygen is far more electronegative the carbon is left short of electrons. Everything these compounds do follows from that. Rotate each one and switch the pi cloud on.

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Compound

Show

TYPE
An aldehyde has the carbonyl group at the end of the chain, so it carries a hydrogen. A ketone has it in the middle, with a carbon on each side. That one hydrogen is the whole difference between them, and it is what the oxidising tests look for.

2. Up and down the oxidation ladder 3D · 17.1

Alcohol, aldehyde, carboxylic acid: three rungs that acidified dichromate climbs and sodium borohydride comes back down. A secondary alcohol and a ketone sit on their own short ladder with no rung above. Click a rung or use the reagent buttons.

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Which ladder?

RUNG

3. Nucleophilic addition of hydrogen cyanide 3D · 17.1

The carbonyl carbon is slightly positive and it is flat, so a nucleophile can reach it from either side. The cyanide ion attacks, the pi electrons move onto the oxygen, and the negative oxygen then takes a proton. The chain grows by one carbon and, very often, the product is chiral. Step through it.

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Starting compound

STEP 1 OF 4

4. Telling them apart at the bench 2D · 17.1

Four reagents, each answering a different question. One shows that a carbonyl group is present at all, two of them pick out the aldehydes, and the last one finds a methyl group next to the carbonyl. Choose a compound and run the tests.

Compound

Tollens’ reagent is silver nitrate in aqueous ammonia and gives a silver mirror. Fehling’s solution is a deep blue copper(II) complex and gives a brick-red precipitate of copper(I) oxide, but only with an aliphatic aldehyde. Both are gentle oxidising agents, and only an aldehyde has the hydrogen that lets it be oxidised.

5. Identify the unknown 2D · 17.1

A bottle with the label missing. You are told the molecular formula and you may run any of the tests. Work out which of the candidates it is, then check your answer. Press for a new sample when you are done.

The sample

MOLECULAR FORMULA

Run a test

Your answer

VERDICT
run some tests first
Start with 2,4-dinitrophenylhydrazine to confirm a carbonyl group, then use Tollens’ reagent to separate the aldehydes from the ketones, and finish with the tri-iodomethane test to find a methyl group next to the carbonyl.
TheLucidSTEM · Cambridge International AS Level Chemistry 9701 · Topic 17 Carbonyl compounds. Every scene runs in the browser; drag to rotate 3D scenes, wheel to zoom. Values are standard textbook data rounded for teaching.

About this lab: Carbonyl compounds

The trigonal planar carbonyl group in 3D with its pi bond and the dipole that leaves the carbon open to attack, the oxidation ladder that links alcohols, aldehydes, ketones and carboxylic acids with the reagents for each step, the nucleophilic addition of hydrogen cyanide animated through the transition to a tetrahedral carbon and a chiral product, the 2,4-DNPH, Tollens, Fehling and tri-iodomethane tests run side by side at the bench, and an unknown compound to identify from its formula and its test results.

Five simulations covering Topic 17: the carbonyl group in 3D with its pi bond and its dipole, the oxidation ladder from alcohol to aldehyde to acid and back down with sodium borohydride, the nucleophilic addition of hydrogen cyanide stepped through in 3D, the four bench tests that tell aldehydes from ketones, and an unknown to identify from its test results.

Carbonyl compounds is a free, browser-based simulation for Cambridge International AS & A Level Chemistry 9701 (topic 17 Carbonyl compounds). The course is assessed in Paper 1 (Multiple Choice (AS)), Paper 2 (AS Structured), Paper 3 (Advanced Practical), Paper 4 (A Level Structured), Paper 5 (Planning, Analysis, Evaluation). Syllabus for examination in 2025-2027. There are 5 tabs, each a self-contained experiment with its own controls and live readings, and nothing to install: it runs on a laptop, tablet or classroom projector.

Syllabus coverage

Full syllabus map: AS Level Chemistry 9701 topic 17.

How to use this simulation

  1. 1. The carbonyl group. A carbon double bonded to an oxygen.
  2. 2. Up and down the oxidation ladder. Alcohol, aldehyde, carboxylic acid: three rungs that acidified dichromate climbs and sodium borohydride comes back down.
  3. 3. Nucleophilic addition of hydrogen cyanide. The carbonyl carbon is slightly positive and it is flat, so a nucleophile can reach it from either side.
  4. 4. Telling them apart at the bench. Four reagents, each answering a different question.
  5. 5. Identify the unknown. A bottle with the label missing.
  6. The buttons at the end of the tab strip give the scene the whole window (Full screen, Hide controls) and, on a dark stage, a projector-friendly palette (Light scene). Many scenes also have drag handles: drag them to change the set-up directly.

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