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9701 AS Chemistry/ Topic 11 Group 17/ 5 interactive simulations/ drag to rotate 3D scenes

Group 17, made interactive

Five simulations covering Topic 11: colour, state and volatility down the halogens, displacement reactions and the order of oxidising power, the stability and acid strength of the hydrogen halides, the disproportionation of chlorine in water and alkali, and the silver nitrate test for halide ions.

1. Down group 17: colour, state and volatility 3D · 11.1

The halogens are diatomic molecules held together by instantaneous dipole forces. Down the group the molecules have more electrons, so those forces grow and the elements change from gas to liquid to solid. Warm each one and see when it boils.

drag to rotate · molecules drawn to relative size

Halogen

20 °C
STATE NOW
COLOUR
BOILING POINT
ELECTRONS PER MOLECULE

2. Displacement reactions and oxidising power 2D · 11.2

A halogen higher in the group will take electrons from the halide ion of one lower down. Pick a halogen and a halide solution, mix them, and see whether the colour changes. The pattern gives the order of oxidising power.

Halogen added

To this halide solution

REACTION?
COLOUR

3. The hydrogen halides: stability and acid strength 3D · 11.2

Down the group the H–X bond gets longer and weaker, so the hydrogen halide is less stable to heat and, in water, a stronger acid. Heat each one with a hot wire and see which one splits.

drag to rotate · bond length drawn to scale

Hydrogen halide

20 °C
BOND ENERGY
BOND LENGTH
DECOMPOSES AT
ACID STRENGTH IN WATER

4. Chlorine in water and in alkali 2D · 11.3

Chlorine disproportionates: the same element is both oxidised and reduced. In water it gives the mixture that treats drinking water; in cold alkali it gives bleach; in hot alkali it goes further still.

Chlorine added to

5. Testing for halide ions 2D · 11.2

Add dilute nitric acid, then silver nitrate solution. Each halide gives a precipitate of a different colour, and they are told apart by whether they dissolve in dilute or concentrated ammonia. Run the test on an unknown.

Sample

The nitric acid is added first to remove carbonate or hydroxide ions, which would also give a precipitate with silver nitrate and spoil the test.
TheLucidSTEM · Cambridge International AS Level Chemistry 9701 · Topic 11 Group 17. Every scene runs in the browser; drag to rotate 3D scenes, wheel to zoom. Values are standard textbook data rounded for teaching.

About this lab: Group 17

The halogens in 3D changing state as you heat them, displacement reactions with the colour changes that give the order of oxidising power, hydrogen halide bond strength and acid strength, chlorine disproportionating in water and in cold and hot alkali, and the silver nitrate and ammonia test for halide ions.

Five simulations covering Topic 11: colour, state and volatility down the halogens, displacement reactions and the order of oxidising power, the stability and acid strength of the hydrogen halides, the disproportionation of chlorine in water and alkali, and the silver nitrate test for halide ions.

Group 17 is a free, browser-based simulation for Cambridge International AS & A Level Chemistry 9701 (topic 11 Group 17, sections 11.1 Physical properties of the Group 17 elements, 11.2 The chemical properties of the halogens and their hydrides, 11.3 Some reactions of the halide ions). The same ideas are examined in Cambridge IGCSE Chemistry 0620 (topic 12 Experimental techniques and chemical analysis, topic 8 The Periodic Table). The course is assessed in Paper 1 (Multiple Choice (AS)), Paper 2 (AS Structured), Paper 3 (Advanced Practical), Paper 4 (A Level Structured), Paper 5 (Planning, Analysis, Evaluation). Syllabus for examination in 2025-2027. There are 5 tabs, each a self-contained experiment with its own controls and live readings, and nothing to install: it runs on a laptop, tablet or classroom projector.

Syllabus coverage

Full syllabus map: AS Level Chemistry 9701 topic 11.

How to use this simulation

  1. 1. Down group 17: colour, state and volatility. The halogens are diatomic molecules held together by instantaneous dipole forces.
  2. 2. Displacement reactions and oxidising power. A halogen higher in the group will take electrons from the halide ion of one lower down.
  3. 3. The hydrogen halides: stability and acid strength. Down the group the H–X bond gets longer and weaker, so the hydrogen halide is less stable to heat and, in water, a...
  4. 4. Chlorine in water and in alkali. Chlorine disproportionates: the same element is both oxidised and reduced.
  5. 5. Testing for halide ions. Add dilute nitric acid, then silver nitrate solution.
  6. The buttons at the end of the tab strip give the scene the whole window (Full screen, Hide controls) and, on a dark stage, a projector-friendly palette (Light scene). Many scenes also have drag handles: drag them to change the set-up directly.

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