AS Level · Topic 3.3
A-Level Chemistry 9701 / Topic 3 / AS

A sea of electrons.

Metal atoms give up their outer electrons, but not to anyone in particular. The electrons spread through the whole lattice and glue the positive ions together, which is why metals conduct, bend and shine.

The key idea

Metallic bonding is the electrostatic attraction between positive metal ions and delocalised electrons. The outer electrons of each atom are released into a “sea” that belongs to the whole giant lattice. The bonding gets stronger as more electrons per atom are delocalised, as the ionic charge rises and as the ions get smaller, so melting points rise from sodium to magnesium to aluminium. The mobile electrons carry current and heat, and because the bonding is non-directional the layers of ions can slide without the lattice breaking.

++++++++ positive ions in a lattice, attracted to delocalised electrons the electrons belong to the whole lattice and are free to move
Fig. 1: positive ions held together by a sea of delocalised electrons
Section 01

Ions in a sea.

Choose sodium, magnesium and then aluminium in the simulator. Count the delocalised electrons each atom contributes and watch how tightly the lattice holds together as that number rises.

MetalIonDelocalised electrons per atomMelting point / °C
sodiumNa+198
magnesiumMg2+2650
aluminiumAl3+3660

Across Period 3 the ions become smaller and more highly charged while the sea becomes denser, so the attraction gets stronger. Down Group 1 the ions get larger with the same charge, so the melting point falls: Li 181 °C, Na 98 °C, K 63 °C.

Section 02

Properties from the sea.

Every classic metal property traces back to electrons that are free to move and bonding that has no fixed direction.

Stage 1 · Learn

Check what the sim just showed you

Four quick checks. Each correct answer earns XP and records this skill on your profile.

Quick check+10 XP

Metallic bonding is the attraction between:

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How many electrons per atom does magnesium contribute to the delocalised sea?

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Why do metals conduct electricity when solid?

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Why can metals be hammered into shape without breaking?

Section 03

Metals and ionic solids compared.

Both are giant lattices held by electrostatic attraction, so students often mix them up. The difference is what the positive ions are attracted to.

MetallicIonic
particlespositive ions and delocalised electronspositive and negative ions
solid conducts?yes, electrons moveno, ions fixed
when hitbends: layers slideshatters: like charges meet
Examiner trap

Say positive ions in a metal lattice, not atoms, and describe the electrons as delocalised. Answers that describe “metal atoms sharing electrons” or “ions attracting each other” do not score: the bond is ion to electron sea.

Stage 2 · Exam

Exam-style questions

Unlocks once the four checks above are done. Worth more XP, written to AS Paper 1 and Paper 2 standard.

Finish the four checks above to unlock the exam questions
Exam style+20 XP

Which metal is expected to have the highest melting point?

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The melting points of the Group 1 metals decrease from lithium to caesium because:

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Which statement correctly compares solid copper and solid sodium chloride?

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Which description of the metallic lattice is correct?

Skill unlocked

Metallic bonding, mastered.

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Go deeper · practice
Six original Cambridge-style questions
Defining metallic bonding, comparing melting points across Period 3 and down Group 1, and explaining conductivity and malleability.