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States of matter

A-Level Chemistry 9701 · Topic 4 revision notes

Everything from the 3 lessons of this topic on a few pages: the key idea of each lesson, the diagram to remember, the points to learn and the traps examiners set. Read it, cover it, test yourself.

  1. Ideal gases and pV = nRT
  2. The liquid state
  3. Lattice structures and properties

1Ideal gases and pV = nRT

Syllabus 4.1

An ideal gas obeys pV = nRT exactly. The kinetic model assumes the molecules are in rapid random motion, have negligible volume compared with the container, have no intermolecular forces, and collide elastically. Real gases behave most ideally at low pressure and high temperature, where the molecules are far apart and move fast. In pV = nRT use SI units: p in Pa, V in m3, T in K and R = 8.31 J K−1 mol−1. Rearranged with n = m ÷ M, the equation gives M = mRT ÷ pV, a way to find Mr of a gas or volatile liquid.

pV / nRT 1.51.00.5 ideal gas attractions win molecular volume wins pressure → a real gas matches the ideal line only at low pressure
Fig. 1: how far a real gas strays from ideal behaviour as the pressure rises

SI units every time.

  • p in Pa, V in m3, T in K.
  • R = 8.31 J K−1 mol−1.
  • M = mRT ÷ pV with m in g gives g mol−1.
  • Ideal: low pressure, high temperature, weak forces.

Watch out!

Keep M in g mol−1 by leaving the mass in grams. And check your answer is sensible: an Mr of 0.058 or 58 000 for a simple liquid means a volume or pressure was not converted. A temperature in °C instead of K is the other classic slip.

2The liquid state

Syllabus 4.2

In a liquid the particles are close together but disordered, moving randomly and sliding past each other while intermolecular forces still hold them. Melting overcomes only some of those forces, but vaporisation separates the particles completely, so the enthalpy change of vaporisation is much larger than that of fusion (water: 41 against 6.0 kJ mol−1). In a closed container, evaporation and condensation reach a dynamic equilibrium; the pressure of the vapour then is the vapour pressure. It rises with temperature, and a liquid boils when its vapour pressure equals the external pressure.

vapour pressure / kPa 0101 atmospheric pressure 078100T / °C ethanol water a liquid boils where its curve reaches the external pressure
Fig. 1: vapour pressure against temperature for ethanol and water

Boiling is where vapour pressure meets outside pressure.

  • Liquid: close, random, mobile particles.
  • ΔHvap > ΔHfus: vaporising separates molecules completely.
  • Vapour pressure: dynamic equilibrium, rises with T.
  • Weaker forces: higher vapour pressure, lower b.p.

Watch out!

Evaporation happens at any temperature, from the surface only; boiling happens at one temperature for a given pressure, throughout the liquid. And when explaining vapour pressure, say the equilibrium is dynamic: both processes continue at equal rates, they do not stop.

3Lattice structures and properties

Syllabus 4.3

A crystalline solid has a regular three-dimensional arrangement of particles called a lattice. There are four types: giant ionic (NaCl, MgO: ions held by ionic bonds), giant metallic (Cu: cations in delocalised electrons), giant molecular or covalent (diamond, graphite, graphene, SiO2: atoms joined by covalent bonds throughout) and simple molecular (I2, ice, C60: molecules held by weak intermolecular forces). To explain a property, name the particles, the force that must be overcome, and how strong it is.

giant ionicgiant metallicgiant molecularsimple molecular NaCl, MgO Cu, Fe, Na diamond, graphite, SiO₂ I₂, ice, C₆₀
Fig. 1: the four types of lattice

Particles, force, strength.

  • Giant ionic: ions, ionic bonds.
  • Giant metallic: cations and delocalised electrons.
  • Giant molecular: atoms, covalent bonds everywhere.
  • Simple molecular: molecules, weak intermolecular forces.

Watch out!

For a giant molecular solid, melting breaks covalent bonds; for a simple molecular solid it overcomes only intermolecular forces. Mixing these up is the most common error in this section. Graphite conducts through delocalised electrons, not ions.

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