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Acids, bases and salts

IGCSE Chemistry 0620 · Topic 7 revision notes

Everything from the 7 lessons of this topic on a few pages: the key idea of each lesson, the diagram to remember, the points to learn and the traps examiners set. Read it, cover it, test yourself.

  1. Properties of acids and bases
  2. pH, indicators and neutralisation
  3. Acids as proton donors, strong and weak acids
  4. Acidic, basic and amphoteric oxides
  5. Preparing soluble salts
  6. Insoluble salts and solubility rules
  7. Hydrated and anhydrous salts

1Properties of acids and bases

Syllabus 7.1

Acids turn blue litmus red, turn methyl orange red and leave thymolphthalein colourless. They react with metals to give a salt and hydrogen, with bases to give a salt and water, and with carbonates to give a salt, water and carbon dioxide. Bases are oxides or hydroxides of metals; soluble bases are alkalis. Alkalis turn red litmus blue, methyl orange yellow and thymolphthalein blue, and release ammonia from ammonium salts. Acids contain H+ ions and alkalis contain OH− ions.

acid + metal → salt + hydrogen Mg + 2HCl → MgCl₂ + H₂ (fizzing; gas pops) acid + base → salt + water CuO + H₂SO₄ → CuSO₄ + H₂O (black solid dissolves, blue solution) acid + carbonate → salt + water + carbon dioxide CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂ (fizzing; limewater milky) alkali + ammonium salt → salt + water + ammonia NaOH + NH₄Cl → NaCl + H₂O + NH₃ (warm; red litmus turns blue)
Fig. 1: the four reaction patterns to learn

Four patterns, one salt.

  • Metal: salt + hydrogen.
  • Base: salt + water.
  • Carbonate: salt + water + carbon dioxide.
  • Indicators: litmus red/blue, methyl orange red/yellow, thymolphthalein colourless/blue.

Watch out!

Metal + acid gives hydrogen; carbonate + acid gives carbon dioxide. Mixing these up is the commonest slip. Also, a base is not always an alkali: say "alkali" only for a base that dissolves in water.

2pH, indicators and neutralisation

Syllabus 7.1

The pH scale runs from 1 to 14. pH 7 is neutral; below 7 is acidic and above 7 is alkaline. Universal indicator gives a different colour for each pH, from red (strongly acidic) through green (neutral) to purple (strongly alkaline). The lower the pH, the higher the concentration of H+ ions. In neutralisation, H+ and OH− ions react to form water, so the pH moves towards 7.

1234567 891011121314 universal indicator colours on the pH scale acidicmore H⁺, lower pH neutralpH 7 alkalinemore OH⁻, higher pH stomach acidvinegarpure watersoapoven cleaner
Fig. 1: the pH scale and universal indicator

Lower number, more acid.

  • pH 7 neutral; below acidic; above alkaline.
  • Universal indicator: red, orange, yellow, green, blue, purple.
  • Lower pH = higher H+ concentration.
  • Neutralisation moves the pH towards 7.

Watch out!

A lower pH means a higher concentration of H+ ions, not a lower one. And pH 7 means neutral only if the solution contains no excess acid or alkali; "more acidic" means a smaller pH number.

3Acids as proton donors, strong and weak acids

Syllabus 7.1

Extended. An acid is a proton donor and a base is a proton acceptor, because an H+ ion is a proton. A strong acid is completely dissociated in water: HCl(aq) → H+(aq) + Cl−(aq). A weak acid is only partially dissociated: CH3COOH(aq) ⇌ H+(aq) + CH3COO−(aq). At the same concentration a weak acid has fewer H+ ions, a higher pH and reacts more slowly.

strong: hydrochloric acid weak: ethanoic acid H⁺Cl⁻H⁺Cl⁻ Cl⁻H⁺Cl⁻H⁺ H⁺Cl⁻H⁺Cl⁻ CH₃COOHCH₃COOH CH₃COOHCH₃COOH CH₃COOH H⁺CH₃COO⁻ completely dissociated HCl → H⁺ + Cl⁻ partially dissociated CH₃COOH ⇌ H⁺ + CH₃COO⁻
Fig. 1: complete and partial dissociation

Donate, accept, dissociate.

  • Acid: proton donor. Base: proton acceptor.
  • Strong: completely dissociated (→).
  • Weak: partially dissociated (⇌).
  • Strength ≠ concentration.

Watch out!

Strong and concentrated are different ideas. Strength is about how completely the acid dissociates; concentration is about how much acid is dissolved per dm3. A dilute solution of a strong acid and a concentrated solution of a weak acid are both possible.

4Acidic, basic and amphoteric oxides

Syllabus 7.2

Basic oxides are oxides of metals, such as calcium oxide and copper(II) oxide; they react with acids to form a salt and water. Acidic oxides are oxides of non-metals, such as carbon dioxide and sulfur dioxide; they react with bases to form a salt and water, and many dissolve in water to give acidic solutions. Extended: amphoteric oxides, such as aluminium oxide and zinc oxide, react with both acids and bases.

basicamphotericacidic most metal oxidesCaO, MgO, CuO,Na₂O react with acidsto form a saltand water some metal oxidesAl₂O₃, ZnO react with acidsAND with bases(Extended) most non-metaloxidesCO₂, SO₂, P₄O₁₀ react with basesto form a saltand water metal on the left of the Periodic Table: basic; non-metal on the right: acidic
Fig. 1: three kinds of oxide

Metal basic, non-metal acidic.

  • Basic oxides (metals) react with acids.
  • Acidic oxides (non-metals) react with bases.
  • Amphoteric (Al2O3, ZnO) react with both.
  • Across a period: basic → amphoteric → acidic.

Watch out!

Not every metal oxide is simply basic: aluminium and zinc oxides are amphoteric. And "acidic oxide" means it reacts with bases; it does not contain hydrogen ions itself. Silicon dioxide is acidic even though it does not dissolve in water.

5Preparing soluble salts

Syllabus 7.3

A salt forms when the hydrogen of an acid is replaced by a metal or ammonium ion. To make a soluble salt from an insoluble solid: add excess solid (metal, base or carbonate) to warm acid, filter off the excess, heat the filtrate to the point of crystallisation, leave to cool, then filter, wash and dry the crystals. For sodium, potassium and ammonium salts, react an acid with an alkali using a titration, then repeat without the indicator and crystallise.

1. reactadd excesscopper(II) oxideto warm dilutesulfuric acid 2. filterremove theunreactedexcess solid 3. concentrateheat the filtrateto the point ofcrystallisation 4. crystalliseleave to cool;filter off thecrystals, washand dry them CuO(s) + H₂SO₄(aq) → CuSO₄(aq) + H₂O(l) excess solid makes sure all the acid is used up, so the crystals are not contaminated with acid
Fig. 1: making copper(II) sulfate crystals by the excess solid method

Excess, filter, crystallise.

  • Insoluble reactant: excess solid method.
  • Na, K, NH4 salts: titration method.
  • Point of crystallisation, then cool; never to dryness.
  • Filter, wash, dry the crystals at the end.

Watch out!

Filter before crystallising, to remove the excess solid; then filter again after crystallising, to separate the crystals from the remaining solution. And the salt is in the filtrate in the first filtration, not in the residue.

6Insoluble salts and solubility rules

Syllabus 7.3

General rules: all sodium, potassium and ammonium salts are soluble; all nitrates are soluble; chlorides are soluble except silver and lead(II) chlorides; sulfates are soluble except barium, calcium and lead(II) sulfates; carbonates and hydroxides are insoluble except those of sodium, potassium and ammonium (calcium hydroxide is slightly soluble). Extended: an insoluble salt is made by precipitation: mix two solutions that contain its ions, then filter, wash and dry the precipitate.

mix solutionsBaCl₂(aq) + Na₂SO₄(aq) precipitatewhite BaSO₄(s) filter, wash, dryresidue = the salt Ba²⁺(aq) + SO₄²⁻(aq) → BaSO₄(s) wash with distilled water to remove the soluble sodium chloride
Fig. 1: making barium sulfate by precipitation

Know the exceptions.

  • Always soluble: Na, K, NH4 compounds and all nitrates.
  • Chlorides: not Ag, Pb. Sulfates: not Ba, Ca, Pb.
  • Carbonates, hydroxides: insoluble except Na, K, NH4.
  • Precipitation: mix, filter, wash residue, dry.

Watch out!

For an insoluble salt the product you want is the residue on the filter paper, not the filtrate: the opposite of the soluble salt method. Nitrates are useful starting materials because they are always soluble; for example, use lead(II) nitrate, not lead(II) chloride, as the source of lead ions.

7Hydrated and anhydrous salts

Syllabus 7.3

A hydrated substance is chemically combined with water; an anhydrous substance contains no water. Water of crystallisation is the water molecules present in the crystals of a hydrated salt, as in CuSO4·5H2O. Heating a hydrated salt drives off this water: blue hydrated copper(II) sulfate becomes white anhydrous copper(II) sulfate. Extended: the number of water molecules, x, can be found from the masses before and after heating.

CuSO₄·5H₂O blue crystals CuSO₄ white powder heat add water heating drives off water; adding water turns it blue and hot water of crystallisation: water molecules that are part of the crystal structure 2.50 g hydrated → 1.60 g anhydrous: 0.90 g of water lost
Fig. 1: hydrated and anhydrous copper(II) sulfate

Mass lost is water.

  • Hydrated: contains water of crystallisation. Anhydrous: none.
  • CuSO4: blue hydrated, white anhydrous.
  • CoCl2: pink hydrated, blue anhydrous.
  • x = mol of water ÷ mol of anhydrous salt.

Watch out!

Hydrated crystals look and feel dry: the water of crystallisation is locked inside the crystal structure, not wetting the surface. And removing it is a chemical change, shown by the colour change, not simply drying.

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