Heating makes particles vibrate more and move a little further apart, so most materials expand. Cooling makes them contract.
The energy needed to raise the temperature of 1 kg of a substance by 1 °C (or 1 K).
During a change of state the temperature stays constant: energy goes into breaking bonds, not raising temperature.
E = m LEvaporation happens from the surface of a liquid at any temperature, not just at boiling.