AS Level · Topic 1.2
A-Level Chemistry 9701 / Topic 1 / AS

Same element, different mass.

Two atoms can share a proton number and still weigh differently. Isotopes have the same electrons, so they react identically, but their extra neutrons show up in every physical measurement and in the decimals of the Periodic Table.

The key idea

Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons, so the same proton number Z and a different nucleon number A. They have the same electron configuration and therefore the same chemical properties. Physical properties that depend on mass, such as density and rate of diffusion, differ slightly. Relative atomic mass is the weighted mean of the isotopic masses, which is why it is rarely a whole number.

p protium 1 p, 0 n, 1 e p n deuterium 1 p, 1 n, 1 e p n n tritium 1 p, 2 n, 1 e same proton number, same electron, different neutron number
Fig. 1: the three isotopes of hydrogen
Section 01

What an isotope is.

Set the abundance of each isotope of chlorine in the simulator and watch the relative atomic mass move. Then switch element and predict, before you look, whether the average mass sits nearer the light or the heavy isotope.

Section 02

Why the chemistry is identical.

Chemical reactions involve the electrons: losing them, gaining them, sharing them. The neutrons in the nucleus take no part.

Stage 1 · Learn

Check what the sim just showed you

Four quick checks. Each correct answer earns XP and records this skill on your profile.

Quick check+10 XP

Isotopes of the same element differ in their number of:

Quick check+10 XP

Isotopes of an element have the same chemical properties because they have the same:

Quick check+10 XP

An atom of 37Cl compared with an atom of 35Cl has:

Quick check+10 XP

The nuclide 146C contains:

Section 03

Notation, and the decimals in the Periodic Table.

Write the nucleon number top left and the proton number bottom left. Relative atomic mass, Ar, is the weighted mean of the isotopic masses, treated fully in Topic 2.

Chlorine is about 75% 35Cl and 25% 37Cl, so Ar = (75 × 35 + 25 × 37) / 100 = 35.5. The average sits three times closer to 35 than to 37 because the lighter isotope is three times more abundant.

Examiner trap

Isotopes have the same number of protons and electrons; only the neutron number differs. Saying that isotopes have a different atomic number, or a different number of electrons, loses the mark. And the mass number is a property of one atom; the relative atomic mass is a property of the natural mixture.

Stage 2 · Exam

Exam-style questions

Unlocks once the four checks above are done. Worth more XP, written to AS Paper 1 and Paper 2 standard.

Finish the four checks above to unlock the exam questions
Exam style+20 XP

Which pair of species are isotopes of each other?

Exam style+20 XP

A sample of chlorine is 75.0% 35Cl and 25.0% 37Cl. Its relative atomic mass is:

Exam style+20 XP

Which property differs between 35Cl2 and 37Cl2?

Exam style+20 XP

Boron has two isotopes, 10B and 11B, and a relative atomic mass of 10.8. The percentage abundance of 11B is:

Skill unlocked

Isotopes, mastered.

This skill is now recorded on your profile. Keep the chain going.

-Rank -Level -Score -Topics
Go deeper · practice
Six original Cambridge-style questions
Defining isotopes, comparing their properties, writing nuclide symbols, and weighted-mean relative atomic mass calculations forwards and in reverse.