Extended · Practice questions · Boyle's Law

Product preserved.

Six original Cambridge-style questions on pV = constant: calculations both ways, the particle explanation, the conditions that must hold, and the shape of the pressure-volume graph.

Original questions All questions on this page are original work, written in the Cambridge IGCSE style. They are not from past papers. They test the same concepts and skills the syllabus rewards.
For every Boyle's Law calculation

p1 V1 = p2 V2, at constant temperature.

01
[2 marks]

State Boyle's Law, including the conditions under which it applies.

  • For a fixed mass of gas at constant temperature, the pressure is inversely proportional to the volume. ✓
  • That is, pV = constant (so p1 V1 = p2 V2). ✓
02
Calculation
[3 marks]

A gas has a volume of 2.0 litres at a pressure of 200 kPa. At constant temperature it is compressed to a volume of 0.5 litres. Calculate the new pressure.

p₂ = p₁V₁ / V₂

p₂ = (200 × 2.0) / 0.5 = 400 / 0.5

p₂ = 800 kPa

Volume cut to a quarter, so pressure is four times bigger.

03
Calculation
[3 marks]

A sealed syringe holds 100 cm³ of gas at a pressure of 300 kPa. The plunger is pulled out, at constant temperature, until the volume is 150 cm³. Calculate the new pressure.

p₂ = p₁V₁ / V₂

p₂ = (300 × 100) / 150 = 30000 / 150

p₂ = 200 kPa

Volume increased, so pressure dropped, as expected.

04
Analysis
[2 marks]

Explain, in terms of particles, why reducing the volume of a fixed mass of gas at constant temperature increases its pressure.

  • In the smaller volume the particles travel a shorter distance between the walls. ✓
  • So they collide with the walls more often, giving a greater force per unit area, which is a higher pressure. ✓
05
Analysis
[2 marks]

Boyle's Law only holds if a particular quantity is kept constant. State this quantity, and explain why the average speed of the particles does not change when the gas is compressed under these conditions.

  • The temperature must be kept constant. ✓
  • The average speed of the particles depends on the temperature, so if the temperature is unchanged the particles keep the same average speed. ✓
06
[2 marks]

A student plots a graph of pressure (y-axis) against volume (x-axis) for a fixed mass of gas at constant temperature. Describe the shape of the graph, and state what the product of the two plotted quantities represents.

  • The graph is a curve that falls steeply at first and then levels off (a downward curve, never reaching the axes). ✓
  • At every point the product pressure × volume is the same constant value. ✓

Mark this once you have attempted all six and checked your working. It records a Practiced badge on the topic and adds a one-time bonus. Revealing the solutions alone does not count.